In order to increase the conduction capability of intrinsic semiconductor, it is better to add some impurities. This process of adding impurities is called as Doping. Now, this doped intrinsic semiconductor is called as an Extrinsic Semiconductor.

A Semiconductor in its extremely pure form is said to be an intrinsic semiconductor. The properties of this pure semiconductor are as follows:

• The electrons and holes are solely created by thermal excitation.
• The number of free electrons is equal to the number of holes.
• The conduction capability is small at room temperature.

An impure semiconductor, which is formed by doping a pure semiconductor is called as an extrinsic semiconductor. There are two types of extrinsic semiconductors depending upon the type of impurity added. They are N-type extrinsic semiconductor and P-Type extrinsic semiconductor.

N-Type Extrinsic Semiconductor

A small amount of pentavalent impurity is added to a pure semiconductor to result in N type extrinsic semiconductor. The added impurity has 5 valence electrons. For example, if Arsenic atom is added to the germanium atom, four of the valence electrons get attached with the Ge atoms while one electron remains as a free electron. This is as shown in the following figure.

All of these free electrons constitute electron current. Hence, the impurity when added to pure semiconductor, provides electrons for conduction.

• In N-type extrinsic semiconductor, as the conduction takes place through electrons, the electrons are majority carriers and the holes are minority carriers.
• As there is no addition of positive or negative charges, the electrons are electrically neutral.
• When an electric field is applied to an N-type semiconductor, to which a pentavalent impurity is added, the free electrons travel towards positive electrode. This is called as negative or N-type conductivity.

P-Type Extrinsic Semiconductor

A small amount of trivalent impurity is added to a pure semiconductor to result in P-type extrinsic semiconductor. The added impurity has 3 valence electrons. For example, if Boron atom is added to the germanium atom, three of the valence electrons get attached with the Ge atoms, to form three covalent bonds. But, one more electron in germanium remains without forming any bond. As there is no electron in boron remaining to form a covalent bond, the space is treated as a hole for This process of adding impurities is called as Doping. Now, this doped intrinsic semiconductor is called as an Extrinsic Semiconductor..